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Visible-light-driven N-centered radicals lead to C-centered α-amino radicals through rare net-1,2-HAT processes, with trapping by silyl enol ethers to access β-amido ketone derivatives. 

In this study, we numerically investigate the effects of the tail-beat phase differences between the trailing fish and its neighboring fish on the hydrodynamic performance and wake dynamics in a two-dimensional high-density school. Foils undulating with a wavy-like motion are employed to mimic swimming fish. The phase difference varies from 0° to 360°. A sharp-interface immersed boundary method is used to simulate flows over the fish-like bodies and provide quantitative analysis of the hydrodynamic performance and wakes of the school. It is found that the highest net thrust and swimming efficiency can be reached at the same time in the fish school with a phase difference of 180°. In particular, when the phase difference is 90°, the trailing fish achieves the highest efficiency, 58% enhancement compared with a single fish, while it has the highest thrust production, increased by 108% over a single fish, at a phase difference of 0°. The performance and flow visualization results suggest that the phase of the trailing fish in the dense school can be controlled to improve thrust and propulsive efficiency, and these improvements occur through the hydrodynamic interactions with the vortices shed by the neighboring fish and the channel formed by the side fish. In addition, the investigation of the phase difference effects on the wake dynamics of schools performed in this work represents the first study in which the wake patterns for systems consisting of multiple undulating bodies are categorized. In particular, a reversed Bénard–von Kármán vortex wake is generated by the trailing fish in the school with a phase difference of 90°, while a Bénard–von Kármán vortex wake is produced when the phase difference is 0°. Results have revealed that the wake patterns are critical to predicting the hydrodynamic performance of a fish school and are highly dependent on the phase difference. 

Numerical studies are presented on the propulsive performance and vortex dynamics of multiple hydrofoils pitching in an in-line configuration. The study is motivated by the quest to understand the hydrodynamics of multiple fin–fin interactions in fish swimming. Using the flow conditions (Strouhal and Reynolds numbers) obtained from a solitary pitching foil of zero net thrust, the effect of phase differences between neighboring foils on the hydrodynamic performance is examined both in position-fixed two- and three-foil systems at Reynolds number Re = 500. It is found that the threefoil system achieves a thrust enhancement up to 118% and an efficiency enhancement up to 115% compared to the two-foil system. Correspondingly, the leading-edge vortex (LEV) and the trailing-edge vortex (TEV) of the hindmost foil combine to form a ‘2P’ wake structure behind the three-foil system with the optimal phase differences instead of a ‘2S’ wake, a coherent wake pattern observed behind the optimal two-foil system. The finding suggests that a position-fixed three-foil system can generate a ‘2P’ wake to achieve the maximum thrust production and propulsive efficiency simultaneously by deliberately choosing the undulatory phase for each foil. When increasing Reynolds number to 1000, though the maximum thrust and propulsive efficiency are not achieved simultaneously, the most efficient case still produces more thrust than most of the other cases. Besides, the study on the effects of three-dimensionality shows that when the foils have a larger aspect ratio, the three-foil system has a better hydrodynamic performance, and it follows a similar trend as the two-dimensional (2D) foil system. This work aids in the future design of high-performance underwater vehicles with multiple controlled propulsion elements.